アレキサンダー・ウィリアムソン
Alexander William Williamson(1824-1904)
ようこそ!フリーイラストポートレートと
歴史の停車場いらすとすてーしょんへ
こちらのページでは ウィリアムソン19世紀に
活躍した世界の化学者XⅧをお楽しみください
ウィリアムソン
イラストポートレート Syusuke Galleryより
![1824-1904を生きた化学者。グリメン(1788-1853)やリービッヒ(1803-1873)に化学を学び、アルコキシドとハロゲン化アルキルを反応させてエーテルを合成する方法(ウィリアムソン合成)を発見し、分子の構造と反応の関係を明らかにした。また長州藩士(伊藤博文ら)5人が密かに渡英した際に自宅に寄留させ、学ぶ環境を提供したことでも知られている。](https://illuststation196.com/wp-content/uploads/2024/06/Alexander-William-Williamson.jpeg)
グリメン(1788-1853)やリービッヒ(1803-1873)に化学を学び
アルコキシドとハロゲン化アルキルを反応させてエーテルを
合成する方法(ウィリアムソン合成)を発見
分子の構造と反応の関係を明らかにした
また長州藩士(伊藤博文ら)5人が密かに渡英した際に
自宅に寄留させ、学ぶ環境を提供したことでも知られている
19世紀の化学
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いらすとすてーしょんでは化学の部屋より19世紀に活躍した世界の化学者と題してイラストポートレートをお届けします
(参考)18世紀に活躍した世界の化学者たち
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(参考)19世紀に活躍した世界の化学者たち(1)
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この特集でお届けしている19世紀に活躍した世界の化学者は↓みてね
(参考)19世紀に活躍した世界の化学者たち(2)
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この特集でお届けしている19世紀に活躍した世界の化学者は↓みてね
(参考)19世紀に活躍した世界の化学者たち(3)
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さて今回はウィリアムソンをお届けします
分子の構造と反応の関係を明らかにしたウィリアムソン
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ウィリアムソンはどんな化学者だったの?
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ウィリアムソンは分子の構造と反応の関係を明らかにした化学者でした
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構造と反応?
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では、順を追ってご紹介します
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アルコキシドとハロゲン化アルキルを反応させてエーテルを合成するウィリアムソン合成を発見しました
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まずはエーテルの合成に成功させたってことなのだね
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このエーテルの合成によって有機化合物の構造理解が進みました
![](https://illuststation196.com/wp-content/uploads/2024/01/Syu-chan.jpeg)
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どの様に進むの?
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少し専門的になるので参考までですが…
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エーテルは、アルキル基 (R-) とアルコキシ基 (RO-) が酸素原子 (O) を介して結合した構造 (R-O-R') を持っています
![](https://illuststation196.com/wp-content/uploads/2024/01/Syu-chan.jpeg)
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このエーテルを合成する反応がウィリアムソン合成なんだね
![](https://illuststation196.com/wp-content/uploads/2022/11/painter.jpg)
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この反応は、SN2置換反応と呼ばれるもので、立体反転という反応が起こるのです
![](https://illuststation196.com/wp-content/uploads/2024/01/Syu-chan.jpeg)
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う〜ん
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このエーテルは2つの有機物が酸素原子を挟んでつながった構造をしているのですが
![](https://illuststation196.com/wp-content/uploads/2022/11/painter.jpg)
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特別な種類の分子同士が ぶつかって、くっつくという反応をウィリアムソンは発見しました
![](https://illuststation196.com/wp-content/uploads/2024/01/Syu-chan.jpeg)
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このことから構造と反応の関係を明らかになっていくのか
![](https://illuststation196.com/wp-content/uploads/2022/11/painter.jpg)
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その通りです!しゅーちゃん
このことから分子の構造と反応の関係が新たに理解されたのです
長州五傑のホスト役
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さて、話は変わるのですが、ウィリアムソンは日本との関わりもあるのですよ
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英国人のウィリアムソンと日本とね〜
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それは1863年長州五傑※と呼ばれた長州藩士5名が幕府禁制の海外渡航を挙行し英国に留学します
※井上馨、井上勝、遠藤謹助、伊藤博文、山尾庸三
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それって、長州ファイブ という映画にもなったよね
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シューちゃん!詳しいですね
その英国での滞在をサポートしたのがウィリアムソンでした
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ウィリアムソンは彼らに自宅を提供して、そしてUniversity College London(UCL)で学ぶ環境を整えたのです
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このメンバーは明治時代にそれぞれ重積を担うのだから、この留学が歴史的にすごいことだったのだろうな
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それを象徴する出来事が2013年の記念イベント※です
※UCL Web pageより
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このメンバーは明治時代にそれぞれ重積を担うのだから、この留学が歴史的にすごいことだったのだろうな
次回はデュワー
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さて、19世紀に活躍した世界の化学者XⅧウィリアムソンは如何でしたか?
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いらすとすてーしょんでは化学の歴史を彩ってきた偉人たちを…
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これからもご紹介していきます
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どうぞお楽しみに!
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デュワーは、極低温研究の分野を切り拓いた化学者でした
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ぜひデュワーのイラストポートレートページにもお越しください
19世紀に活躍した世界の化学者たち
化学・新着偉人(It's New)はこちらから
【化学の部屋|パーキン】19世紀に活躍した世界の化学者XXⅦNew!!
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化学の部屋へようこそ
出身国別、都道府県でお届けしています
化学の部屋 Chemist
化学の部屋Chemistへようこそ。SyusukeGalleryよりイラストポートレートをお届けさせていただきます。
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いらすとすてーしょん検索コーナーh
いらすとすてーしょん検索コーナー
新着偉人(It's New)
新たに公開のイラストポートレートをご覧ください
【化学の部屋|パーキン】19世紀に活躍した世界の化学者XXⅦNew!!
【化学の部屋|クルックス】19世紀に活躍した世界の化学者XXⅥ
いらすとすてーしょん新キャラクター
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2022年より"いらすとすてーしょん"にお立ち寄りいただきありがとうございます
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さて本年いらすとすてーしょんの新キャラクターが誕生しました
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シューちゃんです
![シューちゃんはいらすとすてーしょんのキャラクターです](https://illuststation196.com/wp-content/uploads/2024/01/Syu-chan-1024x1024.jpeg)
![シューちゃんはいらすとすてーしょんのキャラクターです](https://illuststation196.com/wp-content/uploads/2024/01/Syu-chan-1024x1024.jpeg)
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シュー(Syu)です
よろしくね
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3年目を迎えた2024年も皆様に役立つ世界の偉人たちをシューちゃんと共にフリーイラストポートレートをお届けします
いらすとすてーしょんからのお知らせ
![創業76年を迎える総合広告代理業を営む栄光社のイチオシと「いらすとすてーしょん」のコラボレーションが2022年7月1日ついにオープン!イチオシ美術とそのイラストポートレートで贈る作者をぜひご堪能ください](https://illuststation196.com/wp-content/uploads/2022/06/栄光社いらすとすてーしょんコラボPPT-1024x217.jpg)
![創業76年を迎える総合広告代理業を営む栄光社のイチオシと「いらすとすてーしょん」のコラボレーションが2022年7月1日ついにオープン!イチオシ美術とそのイラストポートレートで贈る作者をぜひご堪能ください](https://illuststation196.com/wp-content/uploads/2022/06/栄光社いらすとすてーしょんコラボPPT-1024x217.jpg)
いらすとすてーしょん「Syusuke Gallery」
コラボレーション
「イチオシ」で取り上げられた美術のその作者を
イラストポートレートで贈ります
皆様のお越しをお待ちしております